Fire is a chemical reaction (combustion) involving hot gases and plasma. The three things you need for a flame are oxygen, fuel, and a spark. When the fuel (gaseous wax) and oxygen (from the air) combine in a flame, one of the gases produced is carbon dioxide.

Most people think of carbon dioxide as dry ice, and are fascinated to watch the solid chunk sublimate from solid straight to gas, skipping the liquid state altogether. You’ve seen the curls of dry ice vapor curl down and cover the floor in a thick, wispy fog. Is carbon dioxide always more dense than air, or can we get it to float?

Spectrometers are used in chemistry and astronomy to measure light. In astronomy, we can find out about distant stars without ever traveling to them, because we can split the incoming light from the stars into their colors (or energies) and “read” what they are made up of (what gases they are burning) and thus determine their what they are made of. In this experiment, you’ll make a simple cardboard spectrometer that will be able to detect all kinds of interesting things!

SPECIAL NOTE: This instrument is NOT for looking at the sun. Do NOT look directly at the sun. But you can point the tube at a sheet of paper that has the sun’s reflected light on it.

Usually you need a specialized piece of material called a diffraction grating to make this instrument work, but instead of buying a fancy one, why not use one from around your house?  Diffraction gratings are found in insect (including butterfly) wings, bird feathers, and plant leaves.  While I don’t recommend using living things for this experiment, I do suggest using an old CD.

CDs are like a mirror with circular tracks that are very close together. The light is spread into a spectrum when it hits the tracks, and each color bends a little more than the last. To see the rainbow spectrum, you’ve got to adjust the CD and the position of your eye so the angles line up correctly (actually, the angles are perpendicular).

You’re looking for a spectrum (the rainbow image at left) – this is what you’ll see right on the CD itself. Depending on what you look at (neon signs, chandeliers, incandescent bulbs, fluorescent bulbs, Christmas lights…), you’ll see different colors of the rainbow. For more about how diffraction gratings work, click here.

Materials:

• old CD
• razor
• index card
• cardboard tube

This experiment is for advanced students. Did you know that eating a single peanut will power your brain for 30 minutes? The energy in a peanut also produces a large amount of energy when burned in a flame, which can be used to boil water and measure energy.

Peanuts are part of the bean family, and actually grows underground (not from trees like almonds or walnuts).  In addition to your lunchtime sandwich, peanuts are also used in woman’s cosmetics, certain plastics, paint dyes, and also when making nitroglycerin.

What makes up a peanut?  Inside you’ll find a lot of fats (most of them unsaturated) and  antioxidants (as much as found in berries).  And more than half of all the peanuts Americans eat are produced in Alabama. We’re going to learn how to release the energy inside a peanut and how to measure it.

This experiment is for advanced students.

Ever use soap? Sodium hydroxide (NaOH) is the main component in lye soap. NaOH is mixed with some type of fat (vegetable, pig, cow, etc). Scent can be added for the ‘pretty’ factor and pumice or sand can be added for the manly “You’re coming off my hands and I’ll take no guff” factor. Lots of people still make their own soap and they enjoy doing it.

In this lab, we’re going to investigate the wonders of electrochemistry. Electrochemistry became a new branch of chemistry in 1832, founded by Michael Faraday. Michael Faraday is considered the “father of electrochemistry”. The knowledge gained from his work has filtered down to this lab. YOU will be like Michael Faraday. I imagined he would have been overjoyed to do this lab and see the results. You are soooo lucky to be able to take an active part in this experiment. Here’s what you’re going to do…

You will be “creating” metallic copper from a solution of copper sulfate and water, and depositing it on a negative electrode. Copper is one of our more interesting elements. Copper is a metal, and element 29 on your periodic table. It conducts heat and electricity very well.

Many things around you are made of copper. Copper wire is used in electrical wiring. It has been used for centuries in the form of pipes to distribute water and other fluids in homes and in industry. The Statue of Liberty is a wonderful example of how beautiful 180,000 pounds of copper can be. Yes, it is made of copper, and no, it doesn’t look like a penny…..on the surface. The green color is copper oxide, which forms on the surface of copper exposed to air and water. The oxide is formed on the surface and does not attack the bulk of the copper. You could say that copper oxide protects the copper.

If we don’t have salt, we die. It’s that simple. The chemical formula for salt is NaCl. Broken down, we have Na (sodium) and Cl (chlorine). Either one of these can be fatal in sufficient quantities. When chemically combined, these two deadly elements become table salt. What once could kill now keeps us alive. Isn’t chemistry awesome?

Chlorine, element 17, is called a halogen as are all the elements in the 17^th row. All halogens have similar chemical properties. They are highly reactive nonmetals, and react easily with most metals. Sodium is a metal, and is bonded with sodium in the table salt used in this lab. Besides being found in salt, chlorine has many uses in our world such as killing bacteria in our water, making plastic, cleaning products, and the list goes on. A very useful chemical, and is among the top ten chemicals produced in the United States. Ever since its discovery in 1774, chlorine has been very useful. It is found in nature in sodium chloride, but in very small concentrations. Seawater, the most abundant source of chlorine, has a concentration of only 19g of chlorine per liter.

Magnesium is one of the most common elements in the Earth’s crust. This alkaline earth metal is silvery white, and soft. As you perform this lab, think about why magnesium is used in emergency flares and fireworks. Farmers use it in fertilizers, pharmacists use it in laxatives and antacids, and engineers mix it with aluminum to create the BMW N52 6-cylinder magnesium engine block. Photographers used to use magnesium powder in the camera’s flash before xenon bulbs were available.

Most folks, however, equate magnesium with a burning white flame. Magnesium fires burn too hot to be extinguished using water, so most firefighters use sand or graphite.

We’re going to learn how to (safely) ignite a piece of magnesium in the first experiment, and next how to get energy from it by using it in a battery in the second experiment. Are you ready?

This experiment is for advanced students.

Sparks flying off in all directions…that’s fun. In this lab, we will show how easy it is to produce those shooting sparks. In a sparkler you buy at the store, the filings used are either iron or aluminum.

The filings are placed in a mixture that, when dry, adheres to the metal rod or stick that is used in making the sparkler. The different colors are created by adding different powdered chemicals to the mixture before it dries. When they burn, we get red, blue, white, and green.

First discovered in 1886 by Hans Heinrich Landolt, the iodine clock reaction is one of the best classical chemical kinetics experiments. Here’s what to expect:  Two clear solutions are mixed. At first there is no visible reaction, but after a short time, the liquid suddenly turns dark blue.

Usually, this reaction uses a solution of hydrogen peroxide with sulfuric acid, but you can substitute a weaker (and safer) acid that works just as well:  acetic acid (distilled white vinegar). The second solution contains potassium iodide, sodium thiosulfate (crystals), and starch (we’re using a starch packing peanut, but you can also use plain old cornstarch). Combine one with the other to get the overall reaction, but note that there are actually two reactions happening simultaneously.

Supercooling a liquid is a really neat way of keeping the liquid a liquid below the freezing temperature. Normally, when you decrease the temperature of water below 32^oF, it turns into ice. But if you do it gently and slowly enough, it will stay a liquid, albeit a really cold one!

In nature, you’ll find supercooled water drops in freezing rain and also inside cumulus clouds. Pilots that fly through these clouds need to pay careful attention, as ice can instantly form on the instrument ports causing the instruments to fail. More dangerous is when it forms on the wings, changing the shape of the wing and causing the wing to stop producing lift. Most planes have de-icing capabilities, but the pilot still needs to turn it on.

We’re going to supercool water, and then disturb it to watch the crystals grow right before our eyes! While we’re only going to supercool it a couple of degrees, scientists can actually supercool water to below -43^oF!

This experiment is for advanced students.

In industry, hydrogen peroxide is used in paper making to bleach the pulp before they form it into paper. Biologists, when preparing bones for display, use peroxide to whiten the bones.

At home, 3% peroxide combined with ammonium hydroxide is used to give dark-haired people their desired blonde moment. Peroxide is also used on wounds to clean them and remove dead tissue. Peroxide slows the flow from small blood vessels and oozing in wounds as well.

WARNING!! THIS EXPERIMENT IS PARTICULARLY DANGEROUS!! (No kidding.) This experiment is for advanced students.

We’ve created a video that shows you how to safely do this experiment, although if you’re nervous about doing this one, just watch the video and skip the actual experiment.

The gas you generate with this experiment is lethal in large doses, so you MUST do this experiment outdoors. We’ll be making a tiny amount to show how the chemical reactions of chlorine and hydrogen work.

WARNING!! THIS EXPERIMENT IS PARTICULARLY DANGEROUS!! (No kidding.) This experiment is for advanced students.

We’ve created a video that shows you how to safely do this experiment, although if you’re nervous about doing this one, just watch the video and skip the actual experiment.

Bromine is a particularly nasty chemical, so be sure to very carefully follow the steps we’ve outlined in the video. You MUST do this experiment outdoors. We’ll be making a tiny amount to show how the chemical reactions involving bromine work.

This experiment is for advanced students.

Zinc and Hydrogen are important elements for all of us. Zinc (Zn) metal is element #30 on the periodic table. Lack of zinc in our diets will delay growth of our bodies and can kill.

Hydrogen gas (H) is element #1 on the periodic table. Hydrogen was discovered in the 1500s. In a pure state, hydrogen combustion (in small quantities) is interesting. In large amounts, mixed with oxygen, the explosion can be devastating.

Did you know that supercooled liquids need to heat up in order to freeze into a solid? It’s totally backwards, I know…but it’s true! Here’s the deal:

A supercooled liquid is a liquid that you slowly and carefully bring down the temperature below the normal freezing point and still have it be a liquid. We did this in our Instant Ice experiment.

Since the temperature is now below the freezing point, if you disturb the solution, it will need to heat up in order to go back up to the freezing point in order to turn into a solid.

When this happens, the solution gives off heat as it freezes. So instead of cold ice, you have hot ice. Weird, isn’t it?

Sodium acetate is a colorless salt used making rubber, dying clothing, and neutralizing sulfuric acid (the acid found in car batteries) spills. It’s also commonly available in heating packs, since the liquid-solid process is completely reversible – you can melt the solid back into a liquid and do this experiment over and over again!

The crystals melt at 136^oF (58^oC), so you can pop this in a saucepan of boiling water (wrap it in a towel first so you don’t melt the bag) for about 10 minutes to liquify the crystals.

This experiment is for advanced students. This is a repeat of the experiment: Can Fish Drown? but now we’re going to do this experiment again with your new chemistry glassware.

The aquarium looked normal in every way, except for the fish. They were breathing very fast and sinking head first to the bottom of the tank. They would sink a few inches, then jerk into proper movement again.

The student had to figure out what was wrong. He had set up the aquarium as an ongoing science project, and it was his responsibility to maintain the fish tank. His grade depended on it.

He went to his mom for help. She looked over the setup. “Have you tested the water?”

A quizzical look on his face, the boy said, “Everything is normal nitrates, nitrites, hardness, alkalinity, and pH. The pH was a little acidic, but not outside the proper range.”

This experiment is for advanced students.

This time we’re going to use a lot of equipment… really break out all the chemistry stuff. We’ll need all this stuff to generate oxygen with potassium permanganate (KMNO₄). We will work with this toxic chemical and we will be careful…won’t we?

This experiment shows how a battery works using electrochemistry. The copper electrons are chemically reacting with the lemon juice, which is a weak acid, to form copper ions (cathode, or positive electrode) and bubbles of hydrogen.

These copper ions interact with the zinc electrode (negative electrode, or anode) to form zinc ions. The difference in electrical charge (potential) on these two plates causes a voltage.

Materials:

• one zinc and copper strip
• two alligator wires
• digital multimeter
• one fresh large lemon or other fruit

A ferrofluid becomes strongly magnetized when placed in a magnetic field. This liquid is made up of very tiny (10 nanometers or less) particles coated with anti-clumping surfactants and then mixed with water (or solvents). These particles don’t “settle out” but rather remain suspended in the fluid.

The particles themselves are made up of either magnetite, hematite or iron-type substance.

Ferrofluids don’t stay magnetized when you remove the magnetic field, which makes them “super-paramagnets” rather than ferromagnets. Ferrofluids also lose their magnetic properties at and above  their Curie temperature points.

Ferrofluids are what scientists call “colloidal suspensions”, which means that the substance has properties of both solid metal and liquid water (or oil), and it can change phase easily between the two. (We as show you this in the video below.) Because ferrofluids can change phases when a magnetic field is applied, you’ll find ferrofluids used as seals, lubricants, and many other engineering-related uses.

Here’s a video on toner cartridges and how to make your own homemade ferrofluid. It’s a bit longer than our usual video, but we thought you’d enjoy the extra content.

This experiment is for advanced students.

Purple and white colors, making the whitewash that Tom Sawyer used, and produce an exothermic chemical reaction…..does it get any better?

Limewater is one of the compounds we work with in this experiment. Limewater was used in the old days of America. We’re talking about the 80’s…..the 1880’s.

Traveling medicine shows sold what was called “patent medicines”. These usually had no medicinal properties at all. The man in charge, the salesman of the operation, was called a “huckster”. He would have the one of the people gathered around to listen to him blow into limewater. Their exhaled breath contains carbon dioxide, and the lime water turned cloudy, just like in our experiment.

The man would hold up the glass with the cloudy limewater in it and pour in some of his fantastic remedy. As long as the “medicine” was acidic, it would turn the cloudy limewater clear. This was proof that the remedy would cure whatever ailed the person.

When an atom (like hydrogen) or molecule (like water) loses an electron (negative charge), it becomes an ion and takes on a positive charge. When an atom (or molecule) gains an electron, it becomes a negative ion. An electrolyte is any substance (like salt) that becomes a conductor of electricity when dissolved in a solvent (like water).

This type of conductor is called an ‘ionic conductor’ because once the salt is in the water, it helps along the flow of electrons from one clip lead terminal to the other so that there is a continuous flow of electricity.

This experiment is an extension of the Conductivity Tester experiment, only in this case we’re using water as a holder for different substances, like sugar and salt. You can use orange juice, lemon juice, vinegar, baking powder, baking soda, spices, cornstarch, flour, oil, soap, shampoo, and anything else you have around. Don’t forget to test out plain water for your ‘control’ in the experiment!

This experiment is just for advanced students. If you guessed that this has to do with electricity and chemistry, you’re right! But you might wonder how they work together. Back in 1800, William Nicholson and Johann Ritter were the first ones to split water into hydrogen and oxygen using electrolysis. (Soon afterward, Ritter went on to figure out electroplating.) They added energy in the form of an electric current into a cup of water and captured the bubbles forming into two separate cups, one for hydrogen and other for oxygen.

This experiment is not an easy one, so feel free to skip it if you need to. You don’t need to do this to get the concepts of this lesson but it’s such a neat and classical experiment (my students love it) so you can give it a try if you want to. The reason I like this is because what you are really doing in this experiment is ripping molecules apart and then later crashing them back together.

Have fun and please follow the directions carefully. This could be dangerous if you’re not careful. The image shown here is using graphite from two pencils sharpened on both ends, but the instructions below use wire.  Feel free to try both to see which types of electrodes provide the best results.

Electricity. Chemistry. Nothing in common, have nothing to do with each other. Wrong! Electrochemistry has been a fact since 1774. Once electricity was applied to particular solutions, changes occurred that scientists of the time did not expect.

In this lab, we will discover some of the same things that Farraday found over 300 years ago. We will be there as things tear apart, particles rush about, and the power of attraction is very strong. We’re not talking about dancing, we’re talking about something much more important and interesting….we’re talking about ELECTROCHEMISTRY!

This experiment is for advanced students.

Zinc (Zn), is a metal and it is found as element #30 on the periodic table. We need a little zinc to keep our bodies balanced, but too much is very dangerous.

Zinc is just like the common, everyday substance that we all know as di-hydrogen monoxide (which is the chemical name for water). We need water to survive, but too much will kill us.

DHMO: In chemistry, “Di” equals the number 2; hydrogen is H; mono equals the number one; and oxide is derived from oxygen, and its symbol is O. Put these together and you have Di-hydrogen (H₂), and mono oxygen (O). Put them together, what do you have? Water!

This experiment below is for advanced students. If you’ve ever wondered why hydrogen peroxide comes in dark bottles, it’s because the liquid reacts with sunlight to decompose from H₂O₂ (hydrogen peroxide) into H₂O (water) and O₂ (oxygen). If you uncap the bottle and wait long enough, you’ll eventually get a container of water (although this takes a LOOONG time to get all of the H₂O₂ transformed.)

Here’s a way to speed up the process and decompose it right before your eyes. For younger kids, you can modify this advanced-level experiment so it doesn’t involve flames. Here’s what you do:

If you’ve ever owned a fish tank, you know that you need a filter with a pump. Other than cleaning out the fish poop, why else do you need a filter? (Hint: think about a glass of water next to your bed. Does it taste different the next day?)

There are tiny air bubbles trapped inside the water, and you can see this when you boil a pot of water on the stove. The experimental setup shown in the video illustrates how a completely sealed tube of water can be heated… and then bubbles come out one end BEFORE the water reaches a boiling point. The tiny bubbles smoosh together to form a larger bubble, showing you that air is dissolved in the water.

Materials:

• test tube clamp
• test tube
• lighter (with adult help)
• alcohol burner or votive candle
• right-angle glass tube inserted into a single-hole stopper
• regular tap water

This experiment is for advanced students.

Brimstone is another name for sulfur, and if you’ve ever smelled it burn…..whoa….I’m telling you ….you will see for yourself in this lab. It is quite a smell, for sure. Sulfur is element #16 on the periodic table. Sulfur is used in fertilizer, black powder, matches, and insecticides. In pioneer times sulfur was put into patent medicines and used as a laxative.

To further the evil reputation of sulfur, or brimstone, when sulfur is burned in a coal fired power plant, sulfur dioxide is produced. The sulfur is spewed into the air, where it is reacts with moisture in the air to form sulfuric acid. The clouds get full and need to let go of this sulfuric acid. Down comes the acid rain to wreak havoc on the masonry and plant life below.

Ammonia has been used by doctors, farmers, chemists, alchemists, weightlifters, and our families since Roman times. Doctors revive unconscious patients, farmers use it in fertilizer, alchemists tried to use it to make gold, weightlifters sniff it into their lungs to invigorate their respiratory system and clear their heads prior to lifting tremendous loads. At home, ammonia is used to clean up the ketchup you spilled on the floor and never cleaned up.

The ammonia molecule (NH₃) is a colorless gas with a strong odor – it’s the smell of freshly cleaned floors and windows. Mom is not cleaning with straight ammonia (it’s gas at room temperature because it boils at -28^oF, so the stuff she cleans with is actually ammonium hydroxide, a solution of ammonia and water). Ammonia is found when plants and animals decompose, and it’s also in rainwater, volcanoes, your kidneys (to neutralize excess acid), in the ocean, some fertilizers, in Jupiter’s lower cloud decks, and trace amounts are found in our own atmosphere (it’s lighter than air).

A fundamental concept in science is that mass is always conserved. Mass is a measure of how much matter (how many atoms) make up an object. Mass cannot be created or destroyed, it can only change form.

Materials: paper, lighter or matches with adult help

Pure substances all behave about the same when they are gases. The Ideal Gas Law relates temperature, pressure, and volume of these gases in one simple statement: PV = nRT where P = pressure, V = volume, T = temperature, n = number of moles, and R is a constant.

When temperature increases, pressure and volume increase. Temperature is basically a speedometer for molecules. The faster they are wiggling and jiggling, the higher the temperature and the higher the thermal energy that object has. Pressure is how many pushes a surface feels from the motion of the molecules.

Materials: balloon, freezer, tape measure (optional)

There are three primary states of matter: solid, liquid, and gas.

Solids are the lowest energy form of matter on Earth. Solids are generally tightly packed molecules that are held together in such a way that they can not change their position. The atoms in a solid can wiggle and jiggle (vibrate) but they can not move from one place to another. The typical characteristics that solids tend to have are that they keep their shape unless they are broken and they do not flow.

Liquids have loose, stringy bonds between molecules that hold molecules together but allow them some flexibility. Liquids will assume the shape of the container that holds it.

Gases have no bonds between the molecules. Gases can be squished (compressed), and pure gases all behave the same way. (We’re going to learn more about this with the Ideal Gas Law.)

Materials: can of soda or glass of water

This is a recording of a recent live teleclass I did with thousands of kids from all over the world. I’ve included it here so you can participate and learn, too!

We’re going to be mixing up dinosaur toothpaste, doing experiments with catalysts, discovering the 5 states of matter, and building your own chemistry lab station as we cover chemical kinetics, phase shifts, the states of matter, atoms, molecules, elements, chemical reactions, and much more. We’re also going to turn liquid polymers into glowing putty so you can amaze your friends when it totally glows in the dark. AND make liquids freeze by heating them up (no kidding) using a scientific principle called supercooling,

Materials:

• Chemistry Worksheet
• Aluminum pie plate
• Bowl
• Clear glue or white glue
• Disposable cups
• Goggles & gloves
• Hydrogen peroxide
• OPTIONAL: Instant reusable hand warmer (containing sodium acetate )
• Liquid soap
• Popsicle sticks
• Scissors or pliers
• Sodium tetraborate (also called “Borax”)
• Water bottle
• Yeast
• Yellow highlighter
• Optional: If you want to see your experiments glow in the dark, you’ll need a fluorescent UV black light (about $10 from the pet store – look in cleaning supplies under “Urine-Off” for a fluorescent UV light). UV flashlights and UV LEDs will not work.